Search results for " Dispersion model"
showing 10 items of 12 documents
Temperature effect on phase state and reactivity controls atmospheric multiphase chemistry and transport of PAHs
2017
Atmospheric refrigerator increases the global transport and health risks of carcinogenic PAHs.
Volcanic plume monitoring at Mount Etna by diffusive (passive) sampling
2004
[1] This paper reports the use of diffusive tubes in determining HF, HCl, and SO2 in the volcanic plume of Mount Etna in an attempt to highlight the potential of this method in studying volcanoes. In a first application a network of 18 diffusive tubes was installed on Etna's flanks, aimed at evaluating the atmospheric dispersion of the volcanic plume on a local scale. Results showed a monotonic decrease in volatile air concentrations with distance from the craters (HF from 0.15 to <0.003 μmol m−3, HCl from 2 to <0.01 μmol m−3, and SO2 from 11 to 0.04 μmol m−3), revealing the prevalently volcanic contribution. Matching of SO2/HCl and HCl/HF volatile ratios with contemporaneous measurements a…
Modeling and simulation of dense cloud dispersion in urban areas by means of computational fluid dynamics
2011
Abstract The formation of toxic heavy clouds as a result of sudden accidental releases from mobile containers, such as road tankers or railway tank cars, may occur inside urban areas so the problem arises of their consequences evaluation. Due to the semi-confined nature of the dispersion site simplified models may often be inappropriate. As an alternative, computational fluid dynamics (CFD) has the potential to provide realistic simulations even for geometrically complex scenarios since the heavy gas dispersion process is described by basic conservation equations with a reduced number of approximations. In the present work a commercial general purpose CFD code (CFX 4.4 by Ansys®) is employe…
Atmospheric dispersion of volcanic CO 2 at Vulcano island
2001
Abstract Intensive carbon dioxide emanations occur throughout the island of Vulcano (Aeolian Archipelago, north of Sicily, Italy). The main sources of CO 2 on the island are the hot fumaroles (∼500°C) of the northern ridge of the La Fossa crater, the fumaroles of the Baia di Levante and the emission areas spread out both on the slopes of the cone and in the nearby plain. The carbon dioxide from the soil can be considered as being emitted at air temperature. In this work, CO 2 concentrations in the air over the island are estimated by means of two numerical codes. This paper takes advantage of the parallel knowledge gained from a previously written paper for SO 2 emissions from the La Fossa …
High Resolution Dispersion Modeling near Tunnel Exits
1996
This contribution is concerned with a critical problem which usually occurs at motortraffic tunnels within towns. All exhaust gases accumulating along the entire tunnel distance readily leave the tunnel exits in a very concentrated form. Since modern urban traffic management affords more and more tunnel constructions within highly built-up areas, a reliable calculation of the resulting immission distribution in the neighbourhood of tunnel exits is of great importance.
Axial dispersion model for solid flow in liquid suspension in system of two mixers in total recycle
2006
The measurement of residence time distribution of solid particles in solid-liquid suspension is experimentally difficult. However, the twin system approach is particularly suited for the assessment of particle RTD in flow systems as it allows overcoming some of the usual difficulties generally encountered in this kind of measurement. Twin system consists of two vessels and external piping in total recycle. Experimental results from this system can be evaluated using Z-transforms to derive particle RTD for subsequent testing of alternative flow models. Recently, the axial dispersion model was applied using the "advection diffusion equation" (sometimes called the"diffusion with bulk flow equa…
Dispersion models and air quality data for population exposure assessment to air pollution
2014
Evaluating the extent of exposure to chemicals in absence of continuous measurements of their concentration in air and direct measures of personal exposure is crucial for epidemiological studies. Dispersion models can be a useful tool for reproducing spatio-temporal distribution of contaminants emitted by a specific source. However, they cannot easily be applied to short-term epidemiological studies because they require precise information on daily emission scenarios for a long time, which are generally not available. The aim of this study was to better assess the exposure in the industrial area of Brindisi, which suffers from various critical epidemiological situations, by integrating air …
A new approach for modeling dry deposition velocity of particles
2018
Abstract The dry deposition process is recognized as an important pathway among the various removal processes of pollutants in the atmosphere. In this field, there are several models reported in the literature useful to predict the dry deposition velocity of particles of different diameters but many of them are not capable of representing dry deposition phenomena for several categories of pollutants and deposition surfaces. Moreover, their applications is valid for specific conditions and if the data in that application meet all of the assumptions required of the data used to define the model. In this paper a new dry deposition velocity model based on an electrical analogy schema is propose…
A new tool to process forecast meteorological data for atmospheric pollution dispersion simulations of accident scenarios: A Sicily-based case study
2021
Emergency response plans to mitigate the severity of the accidental release of hazardous compounds in the air have become a primary concern in view of the many adverse events occurred over the years in high-risk plants. To do this, an accurate estimate of forecast meteorological data to be used in dispersion models can be very useful to respond in advance to emergency situations. In this field, FORCALM is a new tool developed to elaborate European Centre for Medium-Range Weather Forecasts data on a 3D computational domain with a high-resolution grid. FORCALM data can be used to perform predictive simulations of impacts on local and regional levels by using CALPUFF modelling system. A case s…
First simultaneous mercury and major volatiles characterization of atmospheric hydrothermal emissions at the Pisciarelli's fumarolic system (Campi Fl…
2020
Abstract Hydrothermal systems with active surface expressions are important natural source of atmospheric mercury. Here we report on the first simultaneous assessment of gaseous elemental mercury (GEM) and major volatiles (H2S and CO2) fluxes from the fumarolic system of Pisciarelli, currently the most active at the Campi Flegrei caldera (CFc), Naples (Italy). This was achieved via a GPS-synchronized Lumex and MultiGAS survey which extends similar investigations reported elsewhere. GEM concentrations measured in the fumarolic emissions were consistently above background air level close to the degassing area (mean ~ 8 ± 3 ng m−3 on average) and ranged up to 12,000 ng m−3. Our data evidenced …